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www.instituteofscience.com [O]
The Weight of Hydrogen Gas (H2). S.H. Shakman
A study involving approximately 200 interdiffusing gas-pairs
supports a value of 4 for the weight of H2 gas in preference to a
value of 2, on a scale of 32 for O2 gas. Table A lists ten
illustrative gas-pairs (A-B); observed diffusion coef-
ficients (Do)*; calculations (Dc) based on viscosity data
and conventionally-appraised molecular weight values*; cal-
culations (Dc') based on atomic numbers per equation Dc'=
8.9585sqrt(WAsqrtWB+WBsqrtWA)/WAWB, when gases (A,B) are assigned
weight values (WA,WB) equal to double the sums of atomic
numbers of component atoms, and 8.9585 adjusts raw calcula-
tions relative to the base of .181 for N2-O2; and alternate
calculations (Dc") identically derived as are Dc' except
that H2 is arbitrarily assigned TABLE A-OBSERVED vs CALCUL-
a WA value of 2 (thus WA and WB ATED DIFFUSION COEFFICIENTS
values approximate convention- A-B Do Dc Dc' Dc"
ally-appraised weight values). H2-N2 .674 .656 .703 1.133
Note that orders of agreement N2-O2 .181 .175 .181-BASE
with observed values exhibited N2-CO2 .144 .130 .149
by Dc' values (based on a value H2-CO .651 .661 .703 1.133
of 4 for the weight of H2 rela- CO-N2 .192 .174 .197
tive to 32 for (2) are (a) com- CO-O2 .185 .175 .181
parable to those exhibited by H2-O2 .697 .689 .651 1.053
the less-directly derived Dc O2-CO2 .139 .128 .137
values and (b) preferable to H2-CO2 .550 .544 .545 .885
those exhibited by Dc" values. CO2-CO .137 .128 .149
*HIRSCHFELDER, J.O., CURTISS, C.F., and BIRD, R.B., Molecu-
lar Theory of Gases and Liquids (1954), p. 579.
(As Newton affirmed,"More is in vain when less will serve.")
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